First-principles study of vibrational and dielectric properties of {\beta}-Si3N4

First-principles calculations have been conducted to study the structural, vibrational and dielectric properties of {\beta}-Si3N4. Calculations of the zone-center optical-mode frequencies (including LO-TO splittings), Born effective charge tensors for each atom, dielectric constants, using density functional perturbation theory, are reported. The fully relaxed structural parameters are found to be in good agreement with experimental data. All optic modes are identified and agreement of theory with experiment is excellent. The static dielectric tensor is decomposed into contributions arising from individual infrared-active phonon modes. It is found that high-frequency modes mainly contribute to the lattice dielectric constant.Comment: 15pages, 1 figure, 5 table

Joint Beamforming for RIS-Assisted Integrated Sensing and Communication Systems

Integrated sensing and communications (ISAC) is an emerging critical technique for the next generation of communication systems. However, due to multiple performance metrics used for communication and sensing, the limited degrees-of-freedom (DoF) in optimizing ISAC systems poses a challenge. Reconfigurable intelligent surfaces (RIS) can introduce new DoF for beamforming in ISAC systems, thereby enhancing the performance of communication and sensing simultaneously. In this paper, we propose two optimization techniques for beamforming in RIS-assisted ISAC systems. The first technique is an alternating optimization (AO) algorithm based on the semidefinite relaxation (SDR) method and a one-dimension iterative (ODI) algorithm, which can maximize the radar mutual information (MI) while imposing constraints on the communication rates. The second technique is an AO algorithm based on the Riemannian gradient (RG) method, which can maximize the weighted ISAC performance metrics. Simulation results verify the effectiveness of the proposed schemes. The AO-SDR-ODI method is shown to achieve better communication and sensing performance, than the AO-RG method, at a higher complexity. It is also shown that the mean-squared-error (MSE) of the estimates of the sensing parameters decreases as the radar MI increases.Comment: 30 pages, 8 figures. This paper has been submitted to IEEE Transactions on Communication